The stress corrosion cracking behaviour of uns n08031 in. Some researchers consider sulfidestress cracking a type of stress corrosion. In the presence of sulfide corrosion products, such. The cracking is affected by environmental conditions such as hydrogen sulfide partial pressure and temperature. It can lead to unexpected sudden failure of normally ductile metals subjected to a tensile stress, especially at elevated temperature. Copper is known to be susceptible to stress corrosion cracking scc under. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Standard material requirements sulfide stress cracking. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material.
Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stresscorrosion cracking. The susceptibility of a high strength low alloy nanostructured steel to sulfide stress corrosion cracking sscc resistance is assessed. A mechanism of hydrogen insertion in the presence of hydrogen sulfide is also presented. Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. H 2 s damage can lead to rapid and extensive damage to metals, including uniform corrosion, pitting, and stepwise cracking. H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. For example, in those sealing materials in which aerobic microbial respiration. They found that the scc cracks usually initiate from corrosion pits and pits nucleate from sulfides. Type i mic involves microorganisms that perform anaerobic respiration, while type ii mic. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Thorough understanding of scc mechanisms of dss in chloride and hydrogen sulfide containing solutions has been useful for material selection in many.
Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. Sulfide stress cracking nace mr01752002, mr0175iso. In addition, a general comparison is made of the testing requirements for the sulfide stress cracking system and for anodic stress corrosion cracking systems involving hydrogen sulfide. In some cases crack initiation has been associated with the formation of a brittle film at the surface of the material, which could have lower ductility due to a different metal. The variation of the name is due to the lack of agreement in the mechanism of failure. The stress can be externally applied or it can be an internal residual stress. Sulfide stress cracking of a pipeline weld in sour gas service. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Stresscorrosion cracking experiments can be categorized as. Stress corrosion cracking is a major issue for rcs system pipes particularly in the weld regions where it is connected to rpv nozzles through safe ends. In this chapter the terms eac and scc are generally interchangeable. These comparisons illustrate the need to design environmental cracking tests which reflect both corrosion mechanism factors and application requirements. Laboratory testing of metals for resistance to sulfide stress. Test frames for applying cyclic loads with the measurement of crack propagation rates.
Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. The mechanism of stress corrosion cracking is not well understood but it is believed to be caused by stress, corrosive environments and susceptible microstructures. In late 2003, it became nace mr0175 iso 15156, petroleum and natural gas industries materials for use in h 2. Therefore, sulfide precipitates, inclusions and stringers can affect. Stress corrosion cracking wikipedia republished wiki 2. Also, scc is a major issue for steam generator tube integrity in many us pwrs. Effect of sulfide on the stress corrosion behaviour of a.
It should not be confused with the term stress corrosion cracking which is an anodic. Reliability of dissimilar metal welds subjected to sulfide stress cracking vol. According to hic and ssc laboratory tests and also with regard to cost of engineering materials, it was evident that the best alternative for the valve body alloy is a217wc9 cast crmo steel. Cracking threshold stress is very high, and is assumed to be about 100kgmm 2. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogenassisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. Introduction hydrogen embrittlement produced by sour gas is a critical issue for oil country tubular goods octg products because it causes failure of these components at load levels much lower than the one determined by classical stress design. Stress corrosion cracking and hydrogen embrittlement of iron base alloys. Sulfide stress cracking ssc vs hydrogen induced cracking. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. A study on the mechanism of stress corrosion cracking of. Many changes have been made with austenitic stainless steels. Tests on statically loaded smooth samples tests on statically loaded precracked samples tests using slowly straining samples more detailed information on these tests can be found in chapter 17, evaluation of stress corrosion cracking, in this book, and in ref 1. Stresscorrosion cracking in aluminum alloys is characteristically intergranular. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production.
Iso 151563 will set new restrictions on uns s174000 174ph october 22, 2014 by mariano. Hydrogen sulfide stress corrosion cracking of stainless steels. According to the electrochemical theory, this requires a condition along grain boundaries that makes them anodic to the rest of the microstructure so that corrosion propagates selectively along them. Specialized stress corrosion cracking testing capabilities. Jul 25, 2017 sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism.
Sulfide stress cracking an overview sciencedirect topics. Thorough understanding of scc mechanisms of dss in chloride and hydrogen sulfidecontaining solutions has been useful for material selection in many. Sridhar ramamurthy and andrej atrens stress corrosion. Wet hydrogen sulfide h2s cracking inspectioneering. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. An industry value that has been developed is nace mr01. Hydrogen sulfide h 2 s is a colorless, flammable, and extremely hazardous gas with a strong rotten egg odor. Sulfide stress cracking how is sulfide stress cracking. Mar 27, 2014 the results indicate that flow control valve body failed due to combination of hydrogeninduced corrosion cracking and sulfide stress corrosion cracking. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism.
Bastien and amiot, mechanism of the effect of ionized. Sulfide stress cracking nace mr01752002, mr0175iso 15156. Corrosionpedia what is sulfide stress cracking ssc. Stress corrosion cracking recommended practices canadian.
This phenomenon is generally termed sulfide stress cracking ssc 1 when operating at room temperature and stress corrosion cracking scc1 when operating at higher temperatures. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Sulfide stress crackingnace mr01752002, mr0175iso 15156 650 te c h n i c a l the details nace mr0175, sulfide stress corrosion cracking resistant metallic materials for oil field equipment is widely used throughout the world. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Hydrogen sulfide is known to cause or assist in the mechanism of cracking with many alloy types including low carbon steels, low alloy steels, alloy steels, tool steels. Al bronze towards stress corrosion cracking has been found to increase with an increase in sulfide ion concentration and in. The results indicate that flow control valve body failed due to combination of hydrogeninduced corrosion cracking and sulfide stress corrosion cracking. To check its resistance to scc and ssc, several tests were performed. Reliability of dissimilar metal welds subjected to sulfide.
Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stress corrosion cracking. Stress corrosion cracking scc is the simultaneous action of a tensile stress and an aggressive environment on an alloy system to produce a brittle fracture in a normally ductile material at stress levels far below engineering design limits. Ian sutton, in plant design and operations second edition, 2017. Notch tensile slow strain rate testing ntssrt method is used to evaluate the threshold stress intensity values kisscc. Only reaction of sulfide, moisture and oxygen is necessary. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. H 2 s can cause sulfide stress cracking of stainless steels. The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made public by cepa in response to a the national energy board of canadas public inquiry mh295 into the problem of stress corrosion cracking scc in oil and gas pipelines. As a form of hydrogen stress cracking, ssc is a cracking mechanism in pipelines, facilities piping and any equipment that comes in contact with sour wet h2s service conditions. Pdf sulfide stress corrosion cracking and hydrogen induced.
Stress corrosion cracking of low strength, low alloy nickel steels in sulfide environments. The primary cause of scc is the residual stress created in the component during manufacturing or fabrication. Low alloy steels, stress corrosion cracking, sulfide stress cracking tagged with. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. The new form of scc was markedly different in both its growth mechanism and in the.
Stress corrosion cracking of highstrength steels abstract. Environmental and metallurgical parameters affecting sulfide. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Hydrogen sulfide stress corrosion cracking in materials for. Stress corrosion cracking the international institute of. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion. Sulphide stress cracking ssc is the biggest concern 9. Metals free fulltext effects of different parameters on initiation. Stress corrosion cracking of copper canisters international nuclear. Fundamentals of stress corrosion cracking researchgate. Corrosionpedia what is stress corrosion cracking scc.
Sulfide stress cracking nace mr01752002, mr0175iso 15156 650 te c h n i c a l the details nace mr0175, sulfide stress corrosion cracking resistant metallic materials for oil field equipment is widely used throughout the world. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Which alloy is for sulfide stress and stress corrosion cracking. Standard test method laboratory testing of metals for. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. The use of dss has been restricted in some cases because of stress corrosion cracking scc, which can initiate and grow in either the ferrite or austenite phase depending on the environment. Although there are several kinds of cracking damage that can occur in metals, delayed brittle fracture of metals resulting from the combined action of corrosion in an aqueous sulfide environment and tensile stresses failure may occur at stresses far below the yield stress is the phenomenon known as ssc. The resistance to chlorideinduced stress corrosion cracking of uns n08031 was tested on ubend specimens according to astm g 30 for a testing time of 2000 hours.
1361 860 1201 474 21 1337 1015 1464 949 370 617 254 1565 1561 109 1027 748 1135 1613 215 1406 872 982 53 1547 542 918 7 955 17 1139 256 104 352 1063 675 1142 799 1124 276 1076 347 220 1025 678 172